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Ask the vet | The hidden mineral thieves costing your farm thousands

30 December 2025
in Ask The Experts
Reading Time: 7 mins read
borehole water windpump

Many farmers depend on borehole water that is often high in minerals such as calcium or iron, often without realising how significantly these elements can hinder the absorption of essential trace minerals. Photo: Landbouweekblad archives

Trace element shortages on farms are not always caused by a lack of supplementation, often the real culprits are hidden antagonists in water, pastures and feed. Many farmers rely on borehole water high in minerals like calcium or iron without realising how powerfully these elements can interfere with the uptake of essential trace minerals. In this Q&A, Drs Willie Smith and Lourens Havenga explain how common antagonists suppress mineral absorption, why this leads to costly subclinical deficiencies, and what producers can do to protect animal health, fertility and performance.

Question: The borehole water on my farm contains a lot of lime (calcium). Could this affect my animals’ health? What about inoculations? 

The Calcium Culprit: Why Your Borehole Water May Be Toxic

Calcium is probably the best-known antagonist to trace elements in Southern Africa and often occurs in borehole water. Successful trace element supplementation is often hampered by significant quantities of antagonists in drinking water, pastures, feed and licks.  

The level of antagonists in animals’ diets are not taken into consideration when trace element supplements – in the form of licks or feeds – are formulated. It is extremely important that antagonists receive the same degree of attention as trace elements do, or more, when calculating and formulating the total diet of ruminants, because too much could lead to a deficiency of trace elements and therefore to poorer production and breeding capacity. Accurately estimating specific levels of antagonists will enable vets and animal experts to develop a more efficient programme for supplementing trace elements.  

The programme should be aimed at optimising trace element functions at important times in the production and breeding cycle of farm animals (drying up, lambing or calving and mating). The suppressive effect of antagonists on the efficiency with which trace elements are absorbed – and thus the efficiency with which their functions in ruminants (by means of enzymes) are expressed – is being understood more and more clearly.  

Research conducted on trace elements has shown that antagonists are a greater problem than was perceived in the past. The American Department of Agriculture has released data that show that supplementing copper and zinc, by means of licks, in areas where there are deficiencies in these elements, made almost no difference to the copper and zinc status of beef cattle. The inability of lick supplementation to raise the copper and zinc status of beef cattle significantly was largely ascribed to the suppressive effects of antagonists. 

In spite of the excessive quantities of calcium present in most borehole water, overabundant quantities of calcium are often found in licks and feeds, if calcium carbonate has been included (because it is inexpensive). Too-high calcium levels depress the absorption of zinc, manganese, copper and selenium. This leads to secondary deficiencies of these trace elements with resulting production and reproduction losses. It is important to know that the old norm – that calcium be added at double the rate of phosphate content in licks and feeds – no longer applies. Calcium should be supplemented only in terms of the needs of the animal. The quantity of calcium in drinking water should also be taken into account.  

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Despite the high calcium content in most borehole water, excessive calcium levels are frequently found in licks and feeds, particularly if calcium carbonate is used due to its low cost. Photo: Landbouweekblad archives

Iron: The Least Recognised Threat to Your Herd

Iron is, apparently, the least acknowledged trace element antagonist in southern Africa. It should not be added to feeds or licks, except in areas where it can definitely be said that there is an iron deficiency. Apart from the fact that borehole water in southern Africa is usually rich in iron, soil and natural grazing in the area usually also contain a fair amount of iron. 

Iron is an antagonist of copper, zinc, manganese and cobalt. Iron’s unfavourable effect on the absorption of copper, zinc and manganese has, as a con sequence, a reduced reproductive efficiency. Iron levels in borehole water should not be higher than 0,2 parts per million (ppm).  

Borehole water contains up to 3 ppm, which is 15 times the maximum acceptable level. And this leads to acute trace element deficiencies. 

The Sulfur Trap: When Essential Becomes Excessive

Sulphur is an antagonist of copper and selenium in particular, and often leads to lower conception rates and reduced calf and lamb percentages. It is extremely important that the correct quantities of sulphur be included in licks and feed because ruminants need it for various functions. Sulphur is also essential for the utilization of non-protein nitrogen (NPN) by microbes in the rumen. The problem is that the total ingestion of sulphur by ruminants is not always taken into account. The total quantity of sulphur in borehole water, cultivated pastures (through fertilisers that contain sulphur), feed and licks that an animal ingests, can easily lead to a too-high intake of sulphur, which in turn can lead to copper and selenium deficiencies.  

Molybdenum: The Regional Risk Factor

Molybdenum is one of the less-important trace element antagonists in southern Africa, but it can sometimes reduce the absorption of copper significantly and so lead to a secondary copper deficiency. It is well-known that the ghanna bush of the Northern Cape contains a lot of molybdenum, which can, at times, cause an acute copper deficiency in the area.  

Why Copper is Your Most Critical Mineral After Phosphate

Because copper is deficient in some areas, and because it is also suppressed by all four of the antagonists mentioned, Professor John Arthington of the University of Florida, USA, considers copper to be the most important mineral, after phosphate, for optimal production in beef cattle. It is essential that attempts be made to ensure that the copper content of the liver remains above 125 ppm (dry matter) in beef cattle, with the aim of ensuring optimal production and breeding capacity.  

The Expensive Truth About Subclinical Deficiencies

According to Professor Lee McDowell of the University of Florida, one of the greatest experts on mineral nutrition of our time, it is important that the goal of supplementing trace elements in ruminants should be to optimise trace element status and functions, not to prevent deficiencies. The full genetic potential of the animal can then be realised. McDonald emphasises that subacute deficiencies in trace elements can occur even if no clinical symptoms of deficiency are present. These subacute deficiencies are the most expensive, and the most difficult, to manage because they often go unnoticed, even though they can at times result in expensive increases in weight, poor breeding and poor production. His most important conclusion, emanating from these statements, is that trace element “deficiencies” are usually not found at farm level because “deficiencies” (non-optimal trace element status) are usually a combination of a series of factors in which antagonists generally play the biggest role. The cause of “deficiency symptoms” (poor production and reproduction) is seldom of such a nature that it can be correctly under stood and interpreted.  

The Solution: Strategic Supplementation and Injection Protocols

At farm level, an attempt should always be made to supplement trace elements effectively with licks and, at the same time, to restrict the concentration of antagonists. It is also essential to administer, subcutaneously, to ruminants, an injectable trace element mixture containing significant quantities of the four most important trace elements for optimal resistance and breeding efficiency (zinc, manganese, selenium and copper) before critical stages in the production or breeding cycle (such as calving or lambing, mating and adapting to feedlots).  

Follow-up injections before critical periods will contribute greatly to combating the factors – especially antagonists – that lead to suboptimal trace element levels and so ensure optimal production and breeding.  

An example of such follow-up injections is the series of Multimin products: Multimin plus Se (reg. no. G1853), Multi min plus Se and Cu for sheep and goats (reg. no. G2145), Multimin plus Se and Cu and Cr for cattle and Multimin plus Se and Cu for cattle (reg. no. G2144).  

References: Arthington, J., 2003: “Mineral Antagonists may Influence Copper Deficiencies”. Feed stuffs, June 16, 2003, page 11. McDowell, L. R., 2003: “Grazing Ruminants Require Free-choice Minerals”. Feedstuffs, November 17, 2003, page 12.

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